Material properties of steels

Iron, like most metals, is found in the Earth's crust only in the form of an ore, ie. combined with other elements such as oxygen or sulfur. Typical iron-containing minerals include Fe2O3—the form of iron oxide found as the mineral hematite, and FeS2—pyrite (fool's gold). Iron is extracted from ore by removing oxygen and combining the ore with a preferred chemical partner such as carbon. This process, known as smelting, was first applied to metals with lower melting points, such as tin, which melts at approximately 250 °C (482 °F) and copper, which melts at approximately 1,000 °C (1,830 °F). In comparison, cast iron melts at approximately 1,370 °C (2,500 °F). All of these temperatures could be reached with ancient methods that have been used since the Bronze Age. Since the oxidation rate itself increases rapidly beyond 800 °C, it is important that smelting take place in a low-oxygen environment. Unlike copper and tin, liquid iron dissolves carbon quite readily. Smelting results in an alloy (pig iron) containing too much carbon to be called steel. The excess carbon and other impurities are removed in a subsequent step.

Other materials are often added to the iron/carbon mixture to produce steel with desired properties. Nickel and manganese in sheet pile add to its tensile strength and make austenite more chemically stable, chromium increases hardness and melting temperature, and vanadium also increases hardness while reducing the effects of metal fatigue. To prevent corrosion, at least 11% chromium is added to steel so that a hard oxide forms on the metal surface; this is known as stainless steel. Tungsten interferes with the formation of cementite, allowing martensite to form with slower quench rates, resulting in high speed steel. On the other hand, sulfur, nitrogen, and phosphorus make steel more brittle, so these commonly found elements must be removed from the ore during processing.

The density of steel varies based on the alloying constituents, but usually ranges between 7.75 and 8.05 g/cm3 (0.280–0.291 lb/in3).
Even in the narrow range of concentrations which make up steel, mixtures of carbon and iron can form a number of different structures, with very different properties. Understanding such properties is essential to making quality steel. At room temperature, the most stable form of iron is the body-centered cubic (BCC) structure α-ferrite. It is a fairly soft metallic material that can dissolve only a small concentration of carbon, no more than 0.021 wt% at 723 °C (1,333 °F), and only 0.005% at 0 °C (32 °F). If the steel contains more than 0.021% carbon then it transforms into a face-centered cubic (FCC) structure, called austenite or γ-iron. It is also soft and metallic but can dissolve considerably more carbon, as much as 2.1% carbon at 1,148 °C (2,098 °F)), which reflects the upper carbon content of steel.